Synthesis and Crystal Structure of an Oxorhenium(v) Complex Containing a Tridentate Imidazole Ligand
نویسندگان
چکیده
The reaction of equimolar amounts of (n-Bu4N)[ReOCl4] and 2-(1-ethanolthiomethyl)-1methylimidazole (Htmi) in acetonitrile yielded cis-[ReOCl2(tmi)]. An X-ray diffraction study shows that tmi ̄ coordinates as a uninegative N,S,O-tridentate ligand to give distorted octahedral geometry around the rhenium(V) ion. The three donor atoms occupy a triangular face in an octahedron, with the alcoholate oxygen coordinated trans to the oxo group.
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